Chemistry Final Exam Problems Review Answers

 

1)  For the following reaction, determine how many moles of oxygen gas (O2), are needed to react with each of the given moles of glucose (C6H12O6 ) listed below:

 

     C6H12O6 (s)  +     6 O2(g)   à    6 CO2(g)   +   6 H20(l)

                                                                        Ans

  1. 5 moles C6H12O6                         30 mol O2
  2. 0.05 moles  C6H12O6                                      0.3 mol O2
  3. 2.5 E -6 moles C6H12O6                           1.5 E -5 mol O2

 

2)  A mass of 46.0 grams of solid sodium reacts with 38.0 g of fluorine gas to produce 84.0 g of sodium fluoride [NaF(s)].

a. Write a balanced equation for this reaction.                              2 Na + F2 à 2 NaF

b. Calculate the number of moles of each substance.                 2.00 mol Na, 1.00 mol F2, 2.00 mol NaF

 

3)  If 17.5 g of zinc metal are reacted with phosphoric acid [H3PO4(aq)],  then

zinc (II) phosphate [Zn3(PO4)2 ] and hydrogen gas are produced.                 Zn(s)  +  H3PO4(aq) à  Zn3(PO4)2  + H2

a.       How many moles of phosphoric acid are required?                  0.178 mol H3PO4

b.       If the phosphoric acid is a 3.00 molar solution, how many liters are needed?     0.0593 L H3PO4

c.       What mass of zinc phosphate will be produced?                     34.4 g Zn3(PO4)2 

d.       How many moles of hydrogen gas will be given off?                  0.268 mol H2

 

4)  What volume of 0.60 M copper(II) sulfate [CuSO4(aq)] will react with 45 mL of 1.5 M sodium hydroxide [NaOH(aq)] to form copper(II) hydroxide [Cu(OH)2(s)] and sodium sulfate [Na2SO4(aq)]?

 

CuSO4(aq) +  2 NaOH(aq)   à   Cu(OH)2(s)    +    Na2SO4(aq)

 

Ans: 56 mL CuSO4

 

 

5)  Explain why the percent yield of a product in a reaction is usually less than 100.

 

If all chemicals are 100% pure, and all react with no atoms lost, the yield is 100%.  Ususally some atoms are lost or impurities are present.  Therefore the yield is frequently less than 100%.  If the apparent yield is more than 100%, there must be some impurity present in the product.

 

6)  If 5.45 g of potassium chlorate [KClO3(s)] are decomposed to form potassium choride [KCl(s)], then 1.95 g of oxygen gas (O2) are also given off.           2 KClO3 à  2 KCl  +  3  O2

a.       Calculate the theoretical yield of oxygen.       2.13 g O2

b.       Calculate the percent yield of oxygen.         % yield   =  actual yield             =  1.95  x 100   =   91.5%

                                                                                        Theoretical yield         2.13

c.       Explain why the percent yield of oxygen is less than 100.

Some oxygen may have escaped or dissolved in the water, or the KClO2 may not have reacted completely.

 

7)         a.  How many grams of FeI2(s) can be formed when 25.7 g of Fe(s) reacts with 105 g of I2(s)?

            b. Which reactant is the limiter?

c. Which reactant is the excess?  How much excess (in grams)?

 

8)  Using a molecular model, explain why a gas can be easily compressed, while a liquid and a solid cannot.

 

Space between molecules is larger in a gas than in a solid or liquid, thus the molecules can be pushed closer together.

 

9)  The volume of a gas is often referred to as one of the properties that can be measured.  Is this volume simply the sum of all of the individual molecular volumes?  Explain your answer.

 

The volume is not simply the sum of all of the individual molecular volumes.  The molecules of a gas are much smaller than their entire container.  The volume of the gas is the volume a given amount of gas occupies at a given temperature and pressure.

 

10) Explain why the air pressure is greater on Waikiki Beach (on the Pacific Ocean) than it is on top of Mauna Kea, one of Hawaii’s volcanoes.

 

A column of air over a given area at sea level is taller and more massive than a column of air over an equivalent area of the volcano.  Thus air pressure is greater on the beach.

 

11)  Carbon dioxide does not exist in the liquid state unless the pressure is at least 5.1 atm.  Convert this pressure into units of:              a.  torr               3900 torr

b. kPa               520 kPa

 

12)  If air pressure is reduced from normal sea level values (this happens at higher elevations), the boiling point of a liquid falls. For instance, water boils at only 95 degrees Celsius if the atmospheric pressure is 634 mm Hg.  Explain this in terms of intermolecular forces and vapor pressure.  Also, convert this pressure into units of: 

a.       atm             0.834 atm

b.   Pa.             84,500 Pa

 

 

13)  Hydrogen gas is collect by bubbling it through water.  Calculate the partial pressure of the hydrogen gas if:

a.       the total pressure is 94,000 Pa, and the partial pressure of water is 1200 Pa.

            Ans:  94,000 Pa   -  1200 Pa  =  92,800 Pa 

b.       the total pressure is 100.3 kPa, and the partial pressure of water is 2600.

            Ans:  100,300 Pa  - 2600 Pa  =  97,700 Pa

c.       Whose gas law helps to solve this problem?

            Dalton’s law of partial pressures

 

14) In a flask that has a volume of 273 dm3, you have a sample of two noble gases: neon and xenon.  The partial pressure of the neon is 96,950 Pa, and the partial pressure of the xenon is 1.025 atm.  What is the total pressure  (in kPa) exerted by these two gases?          Ans: 200.8 kPa

 

15)  Explain why you must convert the temperature to an absolute temperature scale (such as a Kelvin scale) when you wish to use the direct proportionality of the temperature-volume law (Charle’s Law).

 

You need to convert from Celsius degrees to kelvins to get a plot of temperature versus volume that intercepts the x-axis at the origin.

 

16)  Change the following volumes of gases from the conditions given to the new conditions.  Assume that the pressure and amount of gas is constant.

a.       85 cm3 at 61 degrees C to 35 degrees C

            Ans:     78 cm3

b.       7.3 dm3 form 228 degrees C to –48 degrees Celsius

                        Ans:      3.3 dm3

 

17)  An anaesthesiologist is about to administer gas to a patient.  The gas has a temperature of 22.4 degrees C.  When the gas enters the patient’s body, it is warmed to a temperature of 37.2 degrees C.  Assuming that the gas does not undergo a change in pressure, what percentage increase in volume does the gas experience as it reaches the new temperature?

Ans:  1.05 L          There is a 5.0% increase.

 

18)  A sample of carbon dioxide has a volume of 2.0 dm3 at a temperature of –10 degrees C.  What volume will this sample have when the temperature is increased to 110 degrees C?  Assume that the pressure does not change and that no carbon dioxide leaks from the sample.      Ans:  2.9 dm3

 

 

19) Change the following volumes of gases from the conditions given to the new conditions.  Assume that the temperature and amount of gas is constant.

a.       1.15 E3 cm3 at 75.2 kPa to 14.0 kPa

      Ans:  6.1 E3 cm3

 

b.       94.7 dm3 at 1.00 kPa to 100.0 kPa

                   Ans:  0.947 dm3

 

20)  A 12.7-L sample of gas is under a pressure of 9.3 kPa.  What will be the pressure of the gas when the volume increases to 20.1 L (assume the temperature is held constant).

                        Ans:  5.9 kPa

 

21) A sample of nitrogen gas having a volume of 2.44 dm3 is collected at a pressure of 67.4 kPa.  What volume will the gas occupy when its pressure is changed to 145.1 kPa if the temperature is held constant?

                        Ans: 1.18 dm3

 

22)  What did Avogadro assume to be true about equal volumes of gases if they are held at the same temperature and pressure?

 

Under the same conditions of temperature and pressure, the volumes of reacting gasses are in small whole number ratios.

 

23)  Which of the following sample of gases occupies the largest volume, assuming that each sample is at the same temperature and pressure—50.0 g of neo, 50.0 g of argon, or 50.0 g of xenon?

 

Since neon has the smallest molar mass, 50.0 g of neon has the largest number of atoms and therefore the largest volume.

 

24) What volume of carbon dioxide gas contains the same number of oxygen atoms as 250.0 cm3 of carbon monoxide gas, if each gas sample is measured at the same temperature and pressure?

 

Since CO2 has twice as many O atoms as CO, 250.0 cm3 of CO2 has twice as many O atoms as 250.0 cm3 of CO. Therefore, 125.0 cm3 of CO2 has the same number of O atoms as 250.0 cm3 of CO.

 

25)  Mathematically, the ideal gas law may be expressed as PV = nRT.  What do each of the letters in this equation represent?  Identify the variables and constants.

 

Variables: P-Pressure T-absolute temperature, V- volume, n-moles

Constant: R-ideal gas law constant

 

26) What is the volume in dm3 of 12.0 g of nitrogen gas if the gas is measured at a pressure of 125 kPa and a temperature of 45 degrees C?

            Ans:  9.07 dm3

 

 

27) What mass of carbon dioxide will occupy a volume of 5.5 L at a temperature of 5 degrees C and a pressure of 75 kPa?

            Ans:  7.9 g CO2

 

 

28) What is the temperature of a 0.00893 mol sample of neon gas that has a volume of 302 mL and a pressure of 715 torr?

            Ans: 388K  or 115 degrees C

 

29) A balloon is filled with helium to a volume of 12.5 L.  If the temperature of the gas is 25 degrees C and the pressure is 101 kPa, How many moles of helium are in the balloon?  How many helium atoms are in it?

            Ans:                 Ans: 3.07 E 23 He atoms

 

30)  What is the value of the standard temperature expressed in degrees C and in Kelvin? 

            O degrees C or 273 K

 

31)  What is the value of standard pressure in atm and kPa?

            1.00 atm or 101.325 kPa

 

32)  What volume will 25.0 g of ammonia (NH3) occupy at STP?

            Ans:  32.9 dm3

 

 

33) Cooks sometimes use the fermentation of glucose to produce the gas required to make bread rise, as shown by the following chemical equation:

 

C6H12O6 (s)  +  2 O2(g) à 2 CH3COOH(l)  +  CO2(g)  + 2 H20(l)

 

What mass of glucose is required to produce 150. cm3 of carbon dioxide gas measured at STP?

            Ans:  0.60 g C6H12O6

 

34)  When coke (almost pure carbon) is burned in th presence of air, the product is carbon dioxide in the following equation:

            C(s)  +  O2(g)  à  CO2(g)

 

How many liters of carbon dioxide reproduced from burning 750. g of coke with an excess supply of oxygen?  Assume that the carbon dioxide is measured at STP.

            Ans:  1400 L CO2

 

35) What is meant by the term ideal gas?  What is a real gas?

 

An ideal gas obeys the five conditions of the kinetic molecular theory; a real gas does not obey all these conditions.

 

36)  Gases tend to follow the ideal gas law more closely when their pressure is low than when it is high.  Considering what happens to gas volume under high pressure, why do you suppose this trend is true?

 

The volume of a gas decreases when the pressure increases, so the relative volume occupied by the gas molecules themselves increases.  Under these conditions, a gas violates one of the basic postulates of the kinetic molecular theory (relating to molecular volume).

 

37) According to the kinetic molecular theory, what is different about a sample of xenon gas at 25 degrees C and another sample at 100 degrees C.

 

The atoms are moving faster and have more kinetic energy at 100 degrees C.

 

38) According to the kinetic molecular theory, what is the relationship between the average kinetic energy of a sample of gas molecules and their temperature?  Does it matter what scale you use to express this temperature?

 

The average kinetic energy of a sample of gas molecules is directly proportional to its temperature, provided that the temperature is measured on an absolute scale.

 

39) Suppose you have two balloons filled with air.  The smaller balloon has a volume of 500. mL, while the larger balloon has a volume of 1500. mL.  Both balloons have the same temperature and pressure.  In which balloon (if either) are the nitrogen molecules moving faster, the larger balloon or the smaller?  How do you know?

 

On average, the nitrogen molecules are moving with the same velocity in  both balloons because they are at the same temperature.

 

40) In an experiment, it takes an unknown gas 1.5 times longer to diffuse than the same amount of oxygen gas (O2).  Find the molar mass of the unknown gas.

            Ans: x = 72 g/mol

 

41)  Suppose a gas diffuses 1.41 times as fast as sulfur dioxide at the same temperature and pressure.  What is the molar mass of the unknown gas?

            Ans:  32.3 g/mol

 

42)  Two beams of ions—germanium-74 and selenium-74—pass between a pair of charged plates.  The ions have the same charge, but the velocity of the germanium is twice as large as the velocity of the selenium ions.  Identify which beam will be deflected more and explain your reasoning?

 

The selenium ions are deflected more because they have a smaller velocity and therefore have less momentum.

 

43) Compare and contrast the subatomic particles contained in the following atoms or ions

(identify number of protons, neutrons, and electrons of each).

a.       a barium-137 atom and a barium-137 ion with a 2+ charge

barium – 137 atom     56 protons     81 neutrons     56 electrons

barium – 137 ion        56 protons     81 neutrons     54 electrons

 

b.       a molybdenum-96 atom and a molybdenum-96 ion with a 6+ charge

molybdenum – 96 atom     42 protons     52 neutrons     42 electrons

molybdenum – 96 ion        42 protons     52 neutrons     36 electrons

 

c.       a phosphorus-31 atom and a phosphorus-31 ion with a 3- charge

phosphorus – 31 atom     15 protons     16 neutrons     15 electrons

phosphorus – 31 ion        15 protons     16 neutrons     18 electrons

 

44) List which of the three types of radiation—alpha, beta, or gamma—each of the following describes.

a.       is not deflected by a magnet                                     gamma

b.       has a negative charge                                               beta

c.       moves with the greatest speed                                  gamma

d.       consists of ions                                                       alpha

e.       is similar to light rays                                               gamma

f.         consists of the same particles as cathode rays          beta

 

45) Describe the problem with Rutherford’s model of the atom.

 

The electron must be moving around the nucleus.  However, a charge moving in a circle radiates energy.  If that is true of the electron, it would lose energy and spiral into the nucleus, and the atom would collapse.

 

 

 

 

 

 

 

46) A proton beam, an electron beam, and a neutron beam pass between two charged plates.  Assuming the velocities to be the same, draw a diagram showing the paths of each type of subatomic particle.

 

                            +

e-         

   

n                 

                           

p

                             -

 

 

47)  How are chlorine-37 and calcium-40 similar?

 

Both contain 20 neutrons in the nucleus.

 

48)  List the number of protons, neutrons, and electrons in each of the following ions.

         a.   7 Li+            p 3  n  4     e   2

 

       b.    24 Mg2+        p 12  n  12   e   10

 

       c.    27 Al3+       p 13   n 14    e  10

 

       d.    31 P 3-        p  15   n  16    e  18

 

      e.     127 I-            p  53    n 74   e  54

 

49)  A very bright line in the brightline spectrum of sodium has a wavelength of 5.90 E –7 m.  What is the frequency of this line?

 

            Ans: 5.08 E 14 Hz

 

50)   A radio station broadcasts at a frequency of 105.4 MHz.  What is the wavelength of this electromagnetic wave?

            Ans:  frequency (n) à 3.08 E 15 Hz     wavelength (l) à 9.73 E -8 m

 

            Use  c = l n    and    E  =  h n

 

51)  What must be done to a hydrogen atom to change its 2s electron to a 3s electron?  What happens when a hydrogen atom with a 3s electron becomes a hydrogen atom with a 2s electron?

 

A specific amount of energy must be added to the atom. The same amount of energy is given off in the form of a photon.

 

52) What orbital will the sixth electron of ground-state nitrogen occupy?

            Ans:  2p

 

53) What are the three quantum numbers that describe an orbital?

                   n (energy level or size)

                   l (energy sublevel or shape), and

                   m (orbital or orientation)

 

54) Which of the following statements about orbitals is false?

a.       Orbitals are distributed in space round the nucleus.

b.       Orbitals are regions of space in which electrons are likely to be found.

c.       Orbitals show the path of the electron.

d.       Orbitals are part of one model for atomic structure.

 

Ans:  c is false

 

55)  Write the electron configurations for the following elements: arsenic, krypton, bromine, and phosphorus.

 

As    1s22s2p63s23p64s23d104p3

 

Text Box:   Kr

 

Kr    1s22s2p63s23p64s23d104p6

 

Text Box:   Br

 

Br     1s22s2p63s23p64s23d104p5

 

Text Box:   P

 

P       1s22s2p63s23p3

Text Box:   K+
 
Text Box:   K+
 

 


 56) Write the electron configurations for the following ions: K+, O2-, Br 1-

K+     1s22s2p63s23p6

 

O2-    1s22s2p6

Text Box: O2-

 

 


Text Box:  Br-

 

Br1-  1s22s2p63s23p64s23d104p6

 

57)  Name the elements that correspond to each of the following electron configurations. (Assume all are neutral atoms in their ground states.)

a.       1s22s22p1                 boron

b.       1s22s2                     beryllium

c.       1s22s22p63s23p2        silicon

58)  Write the symbol for the elements found in the following locations.

a.       period 3, Group 3A               Ans: Al

b.       period 1, Group 8A               Ans: He

c.       period 4, Group 2B               Ans: Zn

d.       period 6, Group 5A               Ans: Bi

 

59)  At room temperature, nitrogen is a nonmetallic gas, and bismuth is a solid metal.  Why are they both in Group 5A?

They both have 5 electrons in their outermost s and p orbitals.

 

 

 

 

 

60)  Name the group of elements in the periodic table that has the following outer electron configurations.

a.       s2                                                   alkaline earth metals

b.       s2p5                                                 halogens

c.       electrons filling the d orbital               transition elements (transition metals)

d.       s2p6                                                 nobel gases

 

61) Use the periodic table to determine the electron configuration of the valence electrons for the following representative elements.  (The principal quantum number is the same as the period number, and the total number of s and p electrons is the same as the Group number.)

            a. Ca               

            b.  As

            c. Cs

            d. Ne

            e. Po

Ans:  a.  4s2   b. 4s24p3   c.  6s1  d.  2s22p6    e.  6s26p4

 

62) Predict the common ions formed when atoms of the elements listed gain or lose electrons.  Then name the noble gas with which the ion is isoelectronic.

         a. Mg      b. Cl     c. Al      d. K          e. S          f.  Ba                  g.  P

 

Ans:  a. Mg 2+      isoelectronic with neon

         b.  Cl-        isoelectronic with argon

c.      Al 3+     isoelectronic with neon

d.      K+        isoelectronic with argon

e.      S 2‑      isoelectronic with argon

f.      Ba 2+    isoelectronic with xenon

g.      P 3-      isoelectronic with argon

 

 

63) For which of the following elements do you expect there to be a very large increase, going from the 2nd to the 3rd ionization energy (IE):  Na, Mg, Al?

 

Magnesium.  Between the second and third electron taken away, there will be a large increase in IE because the 3rd electron is a core electron.

 

64)  What trend is observed for the atomic radius of atoms

a.       going down a group?    

Ans: Increases due to adding additional energy levels and the shielding effect of the core electrons.

 

b.       Going left to right across a period?

Ans:  Decreases.  Additional electrons are added to the SAME energy level.  Increased nuclear charge with the same distance and no additional shielding will draw the outer level electrons in more tightly.

 

 

65) How does core electron shielding affect the attraction of the nucleus for the valence electrons?

Electron shielding lessens the force of attraction between the nucleus and valence electrons.

 

66) What is ionization energy, and how is it determined?

Ionization energy is the amount of energy required to remove an electron from a gaseous atom or ion. It can be determined by bombarding gaseous elements with electrons of known energy.

 

 

 

 

 

 

 

67)  Sodium reacts with water to form a basic solution, as the following equation shows.

2 Na(s)  +  2 H20(l)  à  2 NaOH(aq)  +  H2(g)

 

Write the equation for the reactions of the following metals with water:

 

a.       K

2 K (s)  +  2 H20(l)  à  2 KOH(aq)  +  H2(g)

 

b.       Li

2 Li(s)  +  2 H20(l)  à  2 LiOH(aq)  +  H2(g)

 

c.       Ca

 Ca(s)  +  2 H20(l)  à   Ca(OH)2(aq)  +  H2(g)

 

68)  Use the electron-sea model to explain the high electrical conductivity of metals.

 

The electrons are mobile and can carry an electrical current (the valence electrons can move easily between the metallic atoms.

 

69) Explain why fire involving an alkali metal cannot be put out with water.

 

They react with water and with oxygen in the air.

 

70)  What is the most reactive element?

            Ans: fluorine

 

71)  Briefly explain how the potential energy changes as two hydrogen atoms approach each other.

 

As the hydrogen atoms get closer, the attractions get larger and the potential energy falls. At some point, the potential energy is at a minimum.  When the atoms get closer still, the effect of repulsions causes the potential energy to rise.

 

72)  How does an ionic bond form?

 

An electron (or electrons) is (are) transferred from a metal atom to a nonmetal atom and the resulting cation and anion are attracted by electrostatic forces.

 

73)  How does a covalent bond form?

 

One, two, or three electron pairs are shared by two atoms.

 

74) What is a crystal lattice?

 

The structure representing the position that ions occupy in an ionic compound.

 

75) What types of elements usually form an ionic bond?

            metals and nonmetals

 

76) What types of elements usually form a covalent bond?

          nonmetals with other nonmetals

 

77)  Classify bonds in each of the following substances as nonpolar covalent, polar covalent, or ionic.

a.       K2O          ionic

b.       BeO            ionic

c.       NH3             polar covalent

d.       KCl             ionic

e.       CBr4            polar covalent

f.         N2               nonpolar covalent

g.       CS2             nonpolar covalent

 

 

78)  Show the partial distribution in the following bonds:

a.       H—Br

b.       N—O

c.       Be—H

 

 

                  d+              d-

18. a.            H—Br

 

                  d+              d-Text Box: d+

Text Box: d-

 

     b.           H-C

 

                   d+             d-Text Box: d+

Text Box: d-

 

    c.        C – Cl

Text Box: d+
Text Box: d-

 

 

 


                   d-          d+

d.                 N-H

 

                  d+        d-Text Box: d+

  

Text Box: d-

 

e.               N-O

 

                      d+        d-                                

Text Box: d-

 

Text Box: d+

 

 f.                Be-H

 

 

79) Describe the arrangement of the electron pairs for each of the following molecules and predict their shape.

a.       CCl4     

b.       SiH4

c.       AsH3

d.       H2Se

e.       CS2

 

Answers for 79-80:        

                             a. tetrahedral       4 bonded pair of electrons

                             b. tetrahedral        4 bonded pair of electrons

                             c. trigonal pyramidal      3 bonded pair and one lone pair of electrons

                             d. bent                   2 bonded pair and 2 lone pair of electrons

                             e. linear                 2 bonded pair (double covalent bonds around the

 

Polarity of 79 a-e:

      a. nonpolar

      b. nonpolar

      c. polar

      d. polar

      e. nonpolar bonds, polar

 

 

80)  Show the bond dipoles and predict the molecular shape of each of the molecules in question 79.

Ans: see above

81) On a molecular level, describe dipole-dipole intermolecular forces.

Dipole-dipole forces between molecules have medium strength.  They are formed when each molecule has a definite dipole (one end of the molecule having a partial positive charge and one end of the molecule having a partial negative charge).  The partial positive end of one molecule will be attracted to the partial negative end of a different molecule, causing an attractive force between the two molecules.

82)  Explain the origin of dispersion forces between two molecules of nitrogen, N2.

Even though N2 is considered to be a nonpolar molecule (equal pull of each N on the shared pairs of electrons), the electrons are constantly in motion.  At a given second of time, the shared pair may be closer to one of the nitrogen atoms, creating a temporary dipole (instantaneous dipole).  At that moment, one end will have a temporary partial positive charge while the other end has a temporary partial negative charge.  For a moment, this creates at attractive force between one N2 molecule and another N2 molecule.

83)  Describe the relationship between the polarity of individual molecules and the nature and strength of intermolecular forces. 

Polar molecules will have much stronger intermolecular forces than nonpolar molecules.  In fact, the stronger the polarity of the bonds within the molecule, the stronger the intermolecular forces will be.  For example, dipole-dipole forces have medium strength, but molecules with much stronger polar bonds, such as H attached to F, O, or N, will create a very strong dipole-dipole interaction that we call hydrogen bonds (but not true chemical bonds).

84) How do dipole-dipole forces differ from H bonds? 

Dipole-dipole forces are medium strength IMF.  H bonds are also dipole-dipole interactions, but on a much stronger level because of the strong attraction of F, O, and N for the shared pair of electrons when bonded with H. 

85) Place the following in order of strength from least strength to greatest strength:  all chemical bonds, dipole-dipole, H bond, London dispersion forces

Ans: London dispersion forces, dipole-dipole, H bonds, all chemical bonds

All intermolecular forces (London dispersion forces, dipole-dipole, H bonds) will be much weaker than any intramolecular forces (all chemical bonds).

86) Of the following types of solids, order these from least structured to most structured:  ionic, covalent molecular, covalent network, amorphous, metallic.

amorphous, covalent molecular, ionic, metallic, covalent network

87) What effect do intermolecular forces have on the boiling point of a liquid?

The stronger the intermolecular forces, the higher the boiling point.  (The more attraction the molecules have for each other, the less likely they will convert to gas, so more energy will have to be added to the system to reach the boiling point).

88) What is the relationship between boiling point, external pressure, and vapor pressure?

In order for boiling point to be reached, the vapor pressure of the liquid must become equal to the external pressure put on the system.

89)  For a particular substance, why is the molar heat of fusion less than the molar heat of vaporization?

The molar heat of fusion is the energy required to convert a substance from solid to liquid.  In order to do this, the IMF must be lessened. The molar heat of vaporization is the energy required to convert a substance from a liquid to a gas.  Gas particles have lots of space between them with basically no intermolecular forces, so the energy required to take a substance from some intermolecular force to none will be much greater than the energy required to just lessen the intermolecular forces.

90)  Why is the temperature of a substance constant during melting?

The substance is gaining energy in the form of potential energy so that it can change phase.  All molecules must have changed state before the temperature will begin increasing.

91)  What is the relationship between kinetic energy and temperature?

Temperature is a measurement of the average kinetic energy of a substance.  The greater the kinetic energy, the greater the temperature.

92) Why does increasing the temperature increase the vapor pressure of a liquid?

As temperature is increased, the motion of the molecules increases.  As the motion of the molecules increases, the molecules try to spread out more by breaking the intermolecular forces between them, which increases the likelihood of the substance changing to gas phase, thus increasing vapor pressure.

93) Explain why 12 g of steam at 100 degrees C can melt more ice than 12 g of liquid water at 100 degrees C.

12 g of water at 100 degrees Celsius is using some of the energy for phase change and melting, whereas 12 g of  steam at 100 degrees Celsius is using all of the energy it contains to melt the ice.

94) What is the triple point of a substance?

The point at which a slight change in either pressure or temperature or both could force the substance into one of three states—solid, liquid, or gas.

95)  What is an indicator?  A substance that changes color depending on the acidity or basicity of a substance

 

96) What does it mean for an acid or base to be neutralized?  The acid or base is weakened, or brought closer to a neutral pH.  It loses some of its characteristic properties of being an acid or base.

97) On a heating curve, why do some areas increase in temperature and other areas plateau?  Areas that increase in temperature are increasing in kinetic energy; areas that plateau are gaining energy, but in the form of gaining potential energy that can be used to change phase.

98) What does pH measure? hydronium ion concentration (or hydrogen ion concentration)

99) What are the products of a neutralization?    salt and water    (acid + base à  salt  +  water)

100) What types of ionizing radiation exist?  Know the characteristics of each.

alpha decay  (a) --> a particle equivalent in mass and atomic to a He nuclide is released; lowest energy of radiation

beta minus decay  (B-) --> an electron is released; middle energy of radiation

beta plus or positron decay  (B+) --> a positive electron is released;  middle energy of radiation

gamma radiation (g)  --> highest energy of radiation--no mass as part of it

101) Complete the following nuclear equation.  204 Pb  à  200 Hg  +  ____.       0  -1e     What type of decay is this?   alpha

102) Complete the following nuclear equation.  234 Th  à  234 Pa  +  ____.        4  2He   What type of decay is this?   beta minus

103) Complete the following nuclear equation     8 B  à   8 Be   +   _____.        0 +1e   What type of decay is this?  beta positive (positron)

104)  What is the difference between fission and fusion?  Both occur due to unstable nuclei;  Fission occurs when the nucleus is unstable, causing a splittiing of the nuclei resulting in some type of radiactive decay (alpha, beta minus, positron, or gamma) to increase stability of the nucleus. Huge amounts of energy are released.   Fusion is the joining of two nuclei to form one nucleus of larger mass.  For equivalent mass, fusion releases much more energy per gram than fusion does.

 105)  Describe C-14 dating.      see section 19.2 in textbook

 

106)  Describe the following nuclear equation:

 

            106Ag  +  0 -1e  à  106Pd           electron capture